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In this proposal we aim to discover a new way of making complex molecules from simple aromatic startingmaterials. These complex molecules, known as bisorbicillinoids have previously been found to be extremely challenging to prepare by several research groups.... Read more Our approach utilises the new application of a catalyst that is only comprised of organic components - know as an organocatalyst. Organocatalysis is a particularly topical area since the 2021 Nobel Prize for chemistry was awarded to Prof. D. Macmillan and Prof. B. List for their ground breaking work in establishing the field in the early 2000's.
The dearomatisation of stable aromatic building blocks provides rapid routes to often complex natural product frameworks. However, the selective construction of such compounds in a catalytic highly enantioselective fashion remains a long-standing challenge. It is only recently that our group reported preliminary studies on a highly enantioselective organocatalytic route to hydroxylative dearomatisation, exemplified in the synthesis of (+)-biscaravacrol in 61% yield and 99:1 e.r. in one synthetic step from carvacrol. Please see related online paper.
We will develop a novel highly enantioselective route to previously difficult to access natural and non-natural products. This new methodology will give practical access to gram quantities of known bisorbicillinoids and new non-natural analogues which we believe will be a valuable class of compounds for future investigators interested in the biological activity of small molecules. Given our preliminary results and experience with oxaziridinium catalysed processes we are confident that we can successfully achieve the aims and objectives of this proposal.Read less
Program overview
Main Subject
Chemistry
Degree
PhD
Study Level
PHD
Study Mode
On Campus
In this proposal we aim to discover a new way of making complex molecules from simple aromatic startingmaterials. These complex molecules, known as bisorbicillinoids have previously been found to be extremely challenging to prepare by several research groups.... Read more Our approach utilises the new application of a catalyst that is only comprised of organic components - know as an organocatalyst. Organocatalysis is a particularly topical area since the 2021 Nobel Prize for chemistry was awarded to Prof. D. Macmillan and Prof. B. List for their ground breaking work in establishing the field in the early 2000's.
The dearomatisation of stable aromatic building blocks provides rapid routes to often complex natural product frameworks. However, the selective construction of such compounds in a catalytic highly enantioselective fashion remains a long-standing challenge. It is only recently that our group reported preliminary studies on a highly enantioselective organocatalytic route to hydroxylative dearomatisation, exemplified in the synthesis of (+)-biscaravacrol in 61% yield and 99:1 e.r. in one synthetic step from carvacrol. Please see related online paper.
We will develop a novel highly enantioselective route to previously difficult to access natural and non-natural products. This new methodology will give practical access to gram quantities of known bisorbicillinoids and new non-natural analogues which we believe will be a valuable class of compounds for future investigators interested in the biological activity of small molecules. Given our preliminary results and experience with oxaziridinium catalysed processes we are confident that we can successfully achieve the aims and objectives of this proposal.Read less
Admission Requirements
3.2+
6.5+
92+
01 Apr 2025
3 Years
Jan
Apr
Tuition fees
Domestic Students
4,786
-
International Students
27,500
-
Scholarships
Selecting the right scholarship can be a daunting process. With countless options available, students often find themselves overwhelmed and confused. The decision can be especially stressful for those facing financial constraints or pursuing specific academic or career goals.
To help students navigate this challenging process, we recommend the following articles:
Biomimmetic Catalytic Asymmetric Synthesis of the Bisorbicillinoids and Related Products PhD
Loughborough University, Loughborough, United Kingdom
# 301-350QS Subject Rankings
36 monthsProgram duration
27,500 Tuition Fee/year
01 Apr, 2025Application Deadline
Program overview
Main Subject
Chemistry
Degree
PhD
Study Level
PHD
Study Mode
On Campus
Read more Our approach utilises the new application of a catalyst that is only comprised of organic components - know as an organocatalyst. Organocatalysis is a particularly topical area since the 2021 Nobel Prize for chemistry was awarded to Prof. D. Macmillan and Prof. B. List for their ground breaking work in establishing the field in the early 2000's.
The dearomatisation of stable aromatic building blocks provides rapid routes to often complex natural product frameworks. However, the selective construction of such compounds in a catalytic highly enantioselective fashion remains a long-standing challenge. It is only recently that our group reported preliminary studies on a highly enantioselective organocatalytic route to hydroxylative dearomatisation, exemplified in the synthesis of (+)-biscaravacrol in 61% yield and 99:1 e.r. in one synthetic step from carvacrol. Please see related online paper.
We will develop a novel highly enantioselective route to previously difficult to access natural and non-natural products. This new methodology will give practical access to gram quantities of known bisorbicillinoids and new non-natural analogues which we believe will be a valuable class of compounds for future investigators interested in the biological activity of small molecules. Given our preliminary results and experience with oxaziridinium catalysed processes we are confident that we can successfully achieve the aims and objectives of this proposal. Read less
Program overview
Main Subject
Chemistry
Degree
PhD
Study Level
PHD
Study Mode
On Campus
Read more Our approach utilises the new application of a catalyst that is only comprised of organic components - know as an organocatalyst. Organocatalysis is a particularly topical area since the 2021 Nobel Prize for chemistry was awarded to Prof. D. Macmillan and Prof. B. List for their ground breaking work in establishing the field in the early 2000's.
The dearomatisation of stable aromatic building blocks provides rapid routes to often complex natural product frameworks. However, the selective construction of such compounds in a catalytic highly enantioselective fashion remains a long-standing challenge. It is only recently that our group reported preliminary studies on a highly enantioselective organocatalytic route to hydroxylative dearomatisation, exemplified in the synthesis of (+)-biscaravacrol in 61% yield and 99:1 e.r. in one synthetic step from carvacrol. Please see related online paper.
We will develop a novel highly enantioselective route to previously difficult to access natural and non-natural products. This new methodology will give practical access to gram quantities of known bisorbicillinoids and new non-natural analogues which we believe will be a valuable class of compounds for future investigators interested in the biological activity of small molecules. Given our preliminary results and experience with oxaziridinium catalysed processes we are confident that we can successfully achieve the aims and objectives of this proposal. Read less
Admission Requirements
Tuition fees
Domestic Students
International Students
Scholarships
Selecting the right scholarship can be a daunting process. With countless options available, students often find themselves overwhelmed and confused. The decision can be especially stressful for those facing financial constraints or pursuing specific academic or career goals.
To help students navigate this challenging process, we recommend the following articles:
Scholarships to study abroad
Find scholarships to study abroad with our lists of international scholarships – categorized by country, by subject, and by type of student.
Scholarship Applications: Frequently Asked Questions
Get answers to all your questions about scholarship applications, including tips on how to find scholarships and chances of success.
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QS subject rankings
Subject: Chemistry
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Engineering New Materials for Solid-State Cooling Phd
Enhancing Human-Robot Interaction: Leveraging Artificial Intelligence for Emotional Intelligence in Robotics PhD
Unveiling Molecular Mechanisms of the Beneficial Impact of Exercise on Cancer Metabolism PhD
Using the Metabolome to Study Aging and Geroprotectors in 3D Cell Models PhD
Visual Data Mining on Proteins and Biomedicine Crystallisation PhD
Waste-derived Bioplastics for a Circular and Sustainable Food Packaging Economy PhD
Life Sciences and Medicine (5)
Adaptive and Predictive Computational Modelling of Biomaterials: A Digital Twin Framework for Next-Generation Personalised Healthcare PhD
Adaptive and Predictive Computational Modelling of Biomaterials: A Digital Twin Framework for Next-Generation Personalised Healthcare PhD
Biomarkers of Aging PhD
Biomarkers of Aging PhD
Developing Prescription Guidelines for Passive Heat Therapy PhD
Developing Prescription Guidelines for Passive Heat Therapy PhD
Does Socialised Real-Life Body Exposure Promote Body Image Positivity PhD
Does Socialised Real-Life Body Exposure Promote Body Image Positivity PhD
Energy Dissipation In Human Soft Tissue During Impacts PhD
Energy Dissipation In Human Soft Tissue During Impacts PhD
Natural Sciences (13)
Accelerated Screening and Synthesis of New Chemotherapeutic Agents for Pancreatic Cancer PhD
Accelerated Screening and Synthesis of New Chemotherapeutic Agents for Pancreatic Cancer PhD
Bespoke Organometallic Compounds for Anticancer Studies PhD
Bespoke Organometallic Compounds for Anticancer Studies PhD
Bio-based Sustainable Materials for Autonomous Thermal Management in Wearables PhD
Bio-based Sustainable Materials for Autonomous Thermal Management in Wearables PhD
Biomimmetic Catalytic Asymmetric Synthesis of the Bisorbicillinoids and Related Products PhD
Biomimmetic Catalytic Asymmetric Synthesis of the Bisorbicillinoids and Related Products PhD
Climate and Ecological Transitions Hub Studentship PhD
Climate and Ecological Transitions Hub Studentship PhD
Coherent State Methods in Spectral Asymptotics PhD
Coherent State Methods in Spectral Asymptotics PhD
Computational Modelling of Sustainable Alloys PhD
Designing Classroom Tasks To Improve Students’ Learning Of Mathematics PhD
Developing Novel Antibiofilm Coatings for Sustainable Biofilm-Free Surfaces PhD
Development of Hybrid Microcomb Sources with Topologically Protected Dark Resonances for Simultaneous Classical and Quantum PhD
Development of Novel Bicyclopentanes (BCP) Bioisosteres From Bench Stable [1.1.1]-Propellane Precursors PhD
Digital Twins for Biofilm Management PhD
Dispersionless Integrable Systems In 2+1 Dimensions PhD
Social Sciences and Management (5)
An Evaluation of Erasmus+ Sport Projects and Their Impact on EU Sport Policy Development PhD
An Evaluation of Erasmus+ Sport Projects and Their Impact on EU Sport Policy Development PhD
Climate Change, Work Design and Worker Wellbeing Phd
Climate Change, Work Design and Worker Wellbeing Phd
Communication and Social Change (CSC) Hub Studentship PhD
Communication and Social Change (CSC) Hub Studentship PhD
Enhancing Motivation in Sport and Exercise Contexts PhD
Enhancing Motivation in Sport and Exercise Contexts PhD
Out of School Youth Provision: An Analysis of Funding and Operational Resilience within the Sector PhD
Out of School Youth Provision: An Analysis of Funding and Operational Resilience within the Sector PhD